PRIMING OF EXPLOSIVES FOR EFFICIENT BLASTING

PRIMING OF EXPLOSIVES FOR EFFICIENT BLASTING

By: Partha Das Sharma

1. INTRODUCTION:

The massive use of blasting agents such as ANFO, Heavy ANFO etc., in rock breakage has brought about an important development of initiation and priming techniques. This is due to, on one hand, the relative insensitivity of these compounds and, on the other hand, a desire to obtain maximum performance from the energy released by the explosives used in the process.

The detonation process requires initiation energy so that it can develop and majntain stable conditions. The most frequent terminology used in initiation is:

Primer: High strength, sensitive explosive used to initiate the main column in the blasthole. They are cap and detonating cord sensitive, including ones of low core load.

Booster. Powerful explosive charge with no initiation accessory that has two functions:

I. Complete the initiation work of the primer in the explosive column, and

2. Create zones of high energy release along the length of the column.

In the following paragraphs present day knowledge is discussed in order to obtain maximum yield from the explosives.

Detonation pressure is the pressure in the reaction zone as an explosive detonates.It is a significant indicator of the ability of an explosive to produce good fragmentation.A high detonation pressure is one of the desirable characteristics in a primer

 

A blasting agent is an explosive that:Comprises ingredients that by themselves are non-explosive; can only be detonated by a high explosive charge placed within it and not by a detonator.All blasting agents contain the following essential components :

  • Oxidiser – A chemical that provides oxygen for the reaction. Typical oxidisers are ammonium nitrate and calcium nitrate.
  • Fuel – A chemical that reacts with oxygen to produce heat. Common fuels include fuel oil and aluminum.
  • Sensitiser – Provides the heat source (‘hot spot’) to drive the chemical reaction of oxidiser and fuel. Sensitisers are generally small air bubbles or pockets within the explosive.

2. PRIMER AND BOOSTER:

  • Priming a charge is simply positioning a suitable primer within a charge or column of explosives.
  • The object is to provide the primary-initiating explosion needed to detonate the main charge efficiently.
  • If an explosives column is not initiated properly, its optimum energy cannot be generated.
  • A change in the configuration or type of initiation, priming or boosting can lead to a significant increase in blasting efficiency.
  • The terms “primer” and “booster” are often confused.
  • Primer is a unit of cap-sensitive explosive used to initiate other explosives or blasting agents. A primer contains a detonator or other initiating device such as detonating cord.
  • The primer cartridge should be assembled at the work-site.
  • The transport of cap primers is hazardous and is against the regulation of most countries.
  • Priming should be done correctly by experienced shot-firers.
  • The primer cartridge must not be tamped nor dropped into the blasthole.
  • When priming blasting agents such as ANFO, the primer should have a diameter which is close to the diameter of the blasthole.
  • A booster is a cap-sensitive explosive but does not contain a detonator.
  • Its purpose is to maintain or intensify the explosive reaction at a specific point in the explosive charge along a blasthole.
  • It is a specially manufactured explosive that can produce a high velocity of detonation (VOD) such as cast boosters that have VOD of 7,600 m/s.
  • The most common used boosters are the pentolite boosters.
  • A pentolite booster is made up of a mixture pentaerythritol tetranitrate (PETN) and TNT.
ANFO generates a relatively low detonation pressure, but provides very good heave performance. The steady state VOD of ANFO is approximately 4200ms in 310mm diameter blast holes.The steady state detonating velocity is also a function of loading density. Poured ANFO densities range between 0.78 and 0.85 g/cc while pneumatically loaded ANFO can reach densities up to 0.95 g/cc, consequently achieving higher detonation velocities.ANFO is highly insensitive to mechanical actions (shock, friction, impact).

ANFO should not be placed in conditions where heavy impact or excessive heating may occur as detonation is possible especially if under confinement.

ANFO is desensitised by absorbing moisture.

Every explosive has a certain critical diameter below which detonation will not propagate beyond the primer point.

Confined, ANFO’s critical diameter is approximately 1 1/4 inches.

That is, a borehole or column of ANFO less than two inches in diameter will detonate in the immediate area of the primer, but cannot reliably carry the detonation process much beyond that point.

When ANFO reaches its full VOD the strength is given as:

  • The weight strength of ANFO (94.5%/5.5%) is 912 Kcal/Kg and
  • Bulk strength is 730 Kcal/Cum

3. PRIMING:

  • When an explosive column is initiated at a point, the full steady-state VOD is generally attained some distance away from that point.
  • This distance is called the run-up distance.
  • The run-up distance varies between explosives.
  • ANFO has the maximum (about six charge diameters) and PETN/TNT explosives have the least (about one charge diameter) as in fig – 1.

1

Fig – 1

  • A VOD less than 2,000 m/s is not considered stable.
  • Tests carried out by Swedish Detonic Research Foundation (SVEDEFO) showed that a NG based explosives primer cartridge initiates ANFO directly to its full velocity.
  • The same result will be obtained with an AN based emulsion explosive primer, provided that its diameter is close to the blasthole diameter.
  • Figure 2 shows a primer that has a stable detonation velocity greater than the ANFO stable detonation.
  • This will ensure that ANFO will reach its stable velocity in a shorter time and the blasting agent will explode efficiently.

 2

Fig-2

4. PRIMING OF ANFO

  • When ANFO is efficiently primed it rapidly reaches its steady state velocity of detonation and maintains it.
  • The steady state velocity depends on the density, the confinement and particle size of ANFO as well as the blasthole diameter.
  • The VOD increases as the blasthole diameter increases and reaches its highest value at a blasthole diameter of 300 mm.

0

  • The purpose of a primer is to initiate the ANFO so that it rapidly reaches its steady state velocity.
  • The primer may initiate the ANFO with low order velocity (VOD lower than the steady state VOD) or overdrive velocity (VOD higher than the steady state VOD).
  • Low order initiation is caused by a primer being too small or too low detonation pressure.

 3

Fig – 3

  • The velocity distance curve (Figure 3) shows that it takes approximately the length of four blasthole diameters.
  • The low energy initiation in the bottom of the blasthole may have serious effect on the blasting result.
  • Figure 4 shows how various types and sizes of primers affect the distance from the primer at which ANFO reaches steady state VOD.

 4

Fig – 4

  • In general, the closer the primer diameter is to the borehole diameter, the more effective a primer will be in initiating ANFO.

5. TOP VERSUS BOTTOM INITIATION

  • In large diameter blastholes in bench mining, an ANFO charge may have a 10 m column, and its VOD of 4 000 m/s.
  • If this charge is bottom primed, the stemming and the top part of the burden are not affected by the detonation until 2.5 ms after initiation.
  • Thus, the bubble or the gas energy has more time to work near the bottom to move the toe before explosion gases escape through the fractured rock.
  • The practice of bottom priming provides a much lower probability of cut-offs, and hence greatly reduce incidence of misfires.

6. QUALITIES OF A PRIMER

  • Four properties of primer have a significant influence on its performance.
  • Detonation pressure: An effective primer should have a minimum detonation pressure of 5 000 MPa.

 5

Fig – 5

  • Diameter: The primer should match the hole diameter as closely as possible; however, its diameter should not be less than 0.67 times the blasthole diameter.
  • Length: It should be sufficiently long for maximum VOD to be reached (that is, run-up distance shorter than the primer length).
  • Shape: The importance of shape can be seen in Figure 6, which shows the results of a ‘double-pipe tests’.

 6

Fig – 6

7. BOOSTER

  • Sometimes, after detonation, a low sensitivity explosive may show signs of losing the VOD progressively along its column.
  • This may arise when an ANFO charge is contaminated with water.
  • The boosters can be placed at appropriate intervals (about 30 times the blasthole diameter) to increase the VOD along the explosives column.
  • Boosters can be placed at appropriate spots where the ground is especially hard and requires extra pressure for satisfactory breakage.

8. SUMMARY

In the priming of ANFO, the efficiency of a primer is defined by its detonation pressure, dimensions and shape. The higher the detonation pressure, the greater its initiating ability.

When priming blasting agents with holes up to 2 1/2 inches in diameter, a full cartridge of high velocity explosives like 60 percent ammonia gelatin, gels, slurries, or cast primers with a blasting cap, is a sufficient charge.

For larger holes, the priming requires much more care, especially if the hole is wet or decked charges are used. A small quantity of a high-velocity primer is better than a large amount of a lower velocity primer. The detonating velocity of the primer must be greater than or equal to the detonating velocity of the agent for efficient detonation.

The best location for priming a charge is at either end of the charge. The placement of primers anywhere else within the powder column shall never be done if there is not also a bottom primer.

With large diameter holes, the shape of the primers, as well as the strength, is important. The diameter of such primers should approach the diameter of the borehole so that the major portion of the available energy is released to propagate a strong detonation wave along the column.

Therefore, the conditions that a primer should comply with in order to eliminate low detonation velocity zones in the ANFO are: the highest possible detonation pressure and a diameter above 213 that of the charge, approximately. The length of the primer is also important, as the primer itself is initiated by a blasting cap or detonating cord and they have a run-up distance in the detonation velocity zone.

The use of detonator cord as a sole detonant is not recommended, since it could cause deflagration rather than detonation of the charge.

The objective of the primer is to achieve a stable detonation. Neither over-priming or underpriming the agent is desirable. The diameter of the primer must be larger than the critical diameter of the explosive.

Every explosive has a certain critical diameter below which detonation will not propagate beyond the primer point. Confined, ANFO’s critical diameter is approximately 1 1/4 inches. That is, a borehole or column of ANFO less than two inches in diameter will detonate in the immediate area of the primer, but cannot reliably carry the detonation process much beyond that point.

The problem of determining how many primers to use and where to locate primers in an explosive column is a difficult one. Too many unnecessary primers add to the cost of blasting, while too few primers rob the blast’s efficiency. Basically, the primers must be located so that the detonation travels through the entire powder column before any of the gas and pressure is vented.

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Effect of double-primer placement on fragmentation and rock fracture: The double-primer placement is based on the principle of shock wave collision. When two shock waves meet each other, the final pressure is greater than the sum of the initial two pressures. Stress analysis indicates that this should be favorable to rock fracture and fragmentation in blasting. Double-primer placement was tested successfully in various mines by using electronic detonators, aiming to improve rock fragmentation.

It has been experienced, when two primers are placed at different positions in a blasthole and they are initiated simultaneously (with the same timing), shock-wave collision takes place. In other words, the double-primer placement is based on the principle of shock wave collision. When two shock waves collide each other (head on), the final pressure is greater than the sum of the initial two pressures. Stress analysis indicates that this should be favorable to rock fracture and fragmentation in blasting.

Theory on shock wave collision – According to one-dimensional shock wave theory, when one shock wave with pressure P1 meets another shock with pressure P2, the final shock pressure P3 produced is greater than the sum of the pressures of the initial two shock waves, i.e. P3 > P1+P2. This case is called shock wave collision.

A shock wave collision is different from an elastic wave collision. In one-dimensional condition, as an elastic stress wave with stress σ1 meets with another elastic wave with stress σ2, the final stress σ3 produced is equal to the sum of the stresses of the initial two elastic waves, i.e. σ3 = σ1+σ2. In fact, shock wave is not elastic; thus the resultant intensity of pressure is more than double, hence the benefit of fragmentation.

Generally, in the case of double-primer placement, one primer is placed at the bottom (or slightly above bottom) of the borehole and other placed at the middle (not at the collar) of the borehole.

Experiments showed that, the amplitude of stress waves in rock mass due to two-primer placement in a blasthole was much greater than the double of the amplitude of the waves caused by one single primer in a similar blasthole. These experiments indicate potential applications of a two-primer placement in rock blasting.

When electronic detonators came into being, shock collision theory was used to improve fragmentation more precisely.

As fragmentation is improved greatly by placement of double primer in borehole, for side-cast blast and Ring-blast this method of double-priming is very advantageous to get higher percentage of cast (throw) and ore recovery respectively.

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32 thoughts on “PRIMING OF EXPLOSIVES FOR EFFICIENT BLASTING

  1. Dear Paratha Das Sharma: I really applaud your efforts on mining & blasting. The technical informations shared by you are quite interesting & reflect your technical,practical,procedural & operational know how of explosives & blasting.
    I have a query regarding the Fig#4. Please note that explosive A (75 mm Dia) is initiating ANFO less effectively as compare to Eplosives B, C & D,which are having lesser diameter with respect to borehole. The steady VOD state of ANFO is being achieved at approx 300mm form initiation point with explosive A,while with explosive B,C & D the steady state of ANFO VOD is being achieved lesser than 300 mm distance from initiation point. Please reconsider the graph & gude me.

    Thanks
    PHOOL ZEB
    Biafo Industries Ltd,
    Pakistan

  2. what is the best way of breaking up the stemming column part of the hole while blasting, will it work if you prime the bottom part of the hole and also the top part with a smaller booster?

    • In case, upper part of the Blast-hole is Hard and top of explosive charge may be below the Hard portion of rock (Cap Rock) or stemming portion of rock is quite Hard; Decking of charges or ‘Satellite Holes’ can be considered for better fragmentation. In other words, explosives have to be present at the Hard portion of Cap Rock for good fragmentation.

  3. Dear Sir,
    Thank you for the information. Which among the three is better
    [65% AN Prill + 35% Emulsion] (or) [25% AN Prill + 35% Emulsion] (or) 100% Emulsion for a Ferrous, open cast and wet hole.

    Which is better in terms of blasting efficiency and cost?

    Thanks & Regards
    Pakshaal S Shah

  4. Pingback: Priming of explosives for efficient blasting | Mining News

  5. can I ask you please, I have an incident where a blast crew member ran over a booster with a stemming loader, do you in your expert opinion deem this as I do (High Potential) for a serious incident

    • If the booster is unprimmed, i.e., cap or detonator not inserted in the booster, the potential of occurring immature blast (due run over by any vehicle), is lesser. However, as per the safety procedure and rule such type of occurrence should be avoided.
      Had this kind of occurrence been on primed booster this would have been a very dangerous.Blast might have been taken place.

  6. What is the difference in using 150g booster VS 400g booster if all boosters have approx 6000ms VOD?
    Can I use 150g booster in 165mm x 6m hole instead of 400g booster? What about 203mm x 15m hole? If not, why not?

    • PRIMER : Qualities and Quantity
      • Four properties of primer have a significant influence on its performance.
      • Detonation pressure: An effective primer should have a minimum detonation pressure of 5 000 MPa.
      • Diameter: The primer should match the hole diameter as closely as possible; however, its diameter should not be less than 0.67 times the blasthole diameter. Higher grammage of Booster has higher diameter; thus, better with higher diameter of blasthole.
      • Length: It should be sufficiently long for maximum VOD to be reached (that is, run-up distance shorter than the primer length).
      • Quantity of Booster used should be Minimum 0.2 % of Column Charge, in any blasthole.

  7. Dear Sir,

    How to calculate the Detonation pressure of an explosive with available field data ??

    • Detonation Pressure is a measure of the product’s shock wave energy, influenced by the product’s density (latent energy) and detonation velocity (rate of energy release). Pressure Magnitude or Gas Pressure is a measure of the potential expanding-gas energy, influenced by the product’s density (latent gas volume) and the heat and velocity of detonation (rate of gas production and expansion).
      Naturally, a better understanding of the detonation performance of an explosive charge can be gained by directly measuring pressure, temperature and velocity of detonation (VOD) as performance of a blast is directly influenced by the degree of confinement given by the borehole diameter and the surrounding rock mass.
      Reliable instrument for direct field measurement of Detonator pressure of explosives is yet to be established.

  8. Dear Sir,

    Is there any direct relationship of commpressive strength of rock with VOD of explosive or energy released by explosive?

    • The concept is, the best matching of optimum shock wave transmission to the rock occurs when detonation impedance equals the impedance of rock materials. In other words, the concept of impedance matching can be applied to the process of transferring energy from the explosive into the rock.
      The impedance of an explosive is represented by its shock energy production rate. The impedance of rock is represented by the rate at which it can accept the transfer of shock energy.
      Very roughly (for conceptual purposes), Explosive impedance would equate to the density of the explosive multiplied by the detonation velocity of the explosion.
      Rock impedance would equate to the density of the rock multiplied by the velocity of sound in rock (P-wave velocity). Rock wise many authors published empirical equations to relate P-wave velocity with compressive strength of rocks; but varies too much.
      Since the impedance of a given piece of rock is fixed, any attempt at impedance matching would obviously have to entail the selection of an explosive that would more closely match the impedance of the rock. Because calculated impedance values in rock are usually far higher and have a much greater range than those calculated for conventional explosives, a better name for the concept of impedance matching might be impedance approximating.
      To take advantage of the concept, the blaster would select an explosive with a lower impedance value (lower density, lower velocity) when attempting to blast rock with a lower impedance value (lower density, lower velocity) and, conversely select a higher impedance explosive to blast rock with a higher impedance value.
      While impedance approximating will assist you in achieving better blasting results, the structure of the rock (joint systems, etc.) will play a very important part and will usually have a greater effect on blast results. Study the rock structure carefully. Consider it in your blast designs and then select your explosives to match the rock.

  9. Dear Sir,
    will you please simulate it with an example.
    Ex. Limestone have p wave velocity ~ 3000m/s
    And its density of limestone is 2.5
    what should be the best preferable explosive.

    • Example…..
      Rock:
      p-wave velocity of Limestone : 2380 m/s
      Density of Limestone: 2250 kg/m3
      Impedance of Limestone : 5355000 kg /m2 /s
      Explosives:
      Confined VOD of Explosive (ANFO): 4000 m/s
      Density of Explosive (ANFO) : 950 kg/m3
      Impedance of Explosive (ANFO) : 3800000 kg /m2 /s

    • Common explosives used in industry now are ANFO (ammonium nitrate/fuel oil), slurries, and emulsions. Many factors are taken into account when determining what type of blast design or explosive will be used. Rock type, density, and strength are all important factors, as well as fracture condition of the rock, and water conditions.
      Explosives release two kind of energy after blasting: Shock energy and Gas energy. High VOD explosives have more Shock energy and relatively low VOD explosives have low Shock energy and high Gas energy. Tougher rock require high of shock energy explosives to break; whereas high Gas energy explosives are suitable for medium hard and softer rock. Thus, Emulsion explosives having high VOD (unconfined VOD to the range of 4500m/s) are suitable for tougher rock such as Hematite and ANFO having VOD of lower range (unconfined VOD to the range of 3500m/s) are suitable for softer rock such as Limestone.

      • Your work is absolutely inspiring. I am from Canada. I will pursue and succeed in this career. I have so much to learn. Drilling and Blasting has always been an interest of mine because there is so much room for growth and so many avenues to pursue. I can travel the world gaining knowledge.

      • In surface mine blasting, there is tendency to place two primers at different position in a blasthole and they are initiated simultaneously. This result in shock wave collision – have great impact on fragmentation; as resultant shock pressure produced due to such collision is much greater than sum of two initial shock pressures.

        Refer: Rock Fracture and Blasting, Author: Zong-Xian Zhang, (Ch. – 15: Primer placement).

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